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Material Safety Data Sheet |
Schuller Fiber
Glass Mats (Acrylic) |
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MSDS No.1014-04 |
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Product Name: Schuller Fiber Glass Mats |
CAS#: Mixture/None assigned |
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Generic Name: Fiber glass mats w/ acrylic resin |
Formula: Mixture |
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Chemical Name: Mixture |
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Manufacturer: Schuller Mats & Reinforcements |
Telephone: (303) 978-4900 |
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Address: |
A Division of Schuller International, Inc. P.O. Box 5108; Denver, CO 80217-5108 |
Emergency: 1-800-424-9300 |
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Trade Names: Carpet Mats 7606, 7610, 7620; Dura-Glass Battery Mat,
Surfacing Mat, 8100 Series Mat, 8300 Series Mat, 3400 Series Mat |
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Ingredient Name |
CAS # |
% |
Exposure Limit(s) |
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Continuous filament fiberous glass |
65997-17-3 |
70-95 |
1 fiber/co. Schuller Workplace Exposure Guideline 5 mg/m3 respirable
dust (OSHA) 10 mg/m3 total dust (ACGIH) |
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Acrylic based binder |
9011-05-6 |
5-30 |
Not established |
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8400 Series Mat may contain: Residual fromaldehyde |
50-00-0 |
Trace |
0.75 ppm TWA; 2 ppm STEL (OSHA) |
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EMERGENCY
OVERVIEW Under normal
conditions of use, this product is not expected to create any unusual
emergency hazards. Inhalation
of excessive amounts of dust from the product may cause temporary upper
respiratory irritation and/or congestion - remove affected individuals to
fresh air. Skin
irritation may be treated by gently washing affected area with soap and warm
water. Eye
irritation may be treated by flushing eyes with large amounts of water. If
irritation persists, contact a physician. In the
event of fire, use normal fire fighting procedures to prevent inhalation of
smoke and gases. |
Health Hazards:
Summary:
Breathing dust from this product may cause a scratchy throat, congestion, and slight coughing. Getting dust or fibers on the skin, or in the eyes may cause itching, rash, or redness. Due to the physical properties of the continuous filament containing products, the fibers cannot be carried into the lower lung passages when inhaled. Therefore, the inhalation hazard is limited to irritation of the upper respiratory tract (nose, throat, upper airways).
Under conditions of high heat and humidity, formaldehyde gas
may be released from the mat product. Formaldehyde is irritating to the eyes
and respiratory system and has been classified as having carcinogenic
potential. Exposure to formaldehyde may cause skin or respiratory sensitization
(allergy).
Acute
(short-term) health effects:
Dusts, gases, and fibers from this product are mechanical irritants, which means they may cause irritation or scratchiness of the throat, and/or itching in the eyes and skin.
Chronic
(long-term) health effects:
Formaldehyde has been classified as having carcinogenic potential. Exposure to formaldehyde can cause skin or respiratory sensitization.
Target Organs:
Upper respiratory passages, skin, and eyes.
Primary routes
of entry (exposure):
Inhalation (breathing dust or fibers), skin, and eye contact.
Medical
Conditions which may be aggravated:
Pre-existing chronic eye, skin, or respiratory diseases.
Inhalation:
Irritation of the upper respiratory tract, coughing, and congestion may occur in extreme exposures.
Skin Contact:
Temporary irritation (itching) or redness may occur.
Skin
Absorption:
Not applicable.
Ingestion:
This product is not likely to be ingested under normal conditions of use. If the product is ingested, it may cause temporary irritation to the gastrointestinal (GI) tract (especially the stomach).
Eye Contact:
Temporary irritation (itching) or redness may occur.
SECTION 4: FIRST AID
MEASURES:
Inhalation:
Remove to fresh air. Drink water to clear throat, and blow nose to remove fibers.
Skin Contact:
Wash gently with soap and warm water to remove dust and fibers. Wash hands before eating or using the restroom.
Skin
Absorption:
Not expected to occur.
Ingestion:
Product is not intended to be ingested or eaten. If this product is ingested, irritation of the GI (gastrointestinal) tract may occur, and should be treated symptomatically. Rinse mouth with water to remove fibers, and drink plenty of water to help reduce the irritation. No chronic effects are expected following ingestion.
Eye
Contact:
Do not rub or scratch your eyes. Dust particles may cause the lens of the eye to be scratched. Flush eyes with large amounts of water for 5-15 minutes. If irritation persists, contact a physician.
Notes to
Physician:
This product is a mechanical irritant, and is not expected to produce any chronic health effects. Treatment should be directed toward removing the source of irritation with symptomatic treatment as necessary.
No special procedures are expected to be necessary for this product.
Normal fire fighting procedures should be followed to avoid inhalation of smoke
and gases.
Procedures
for containing spill/leaks:
Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant (such as water) - do not dry sweep dust accumulation. These procedures will help to minimize potential exposures.
Waste
Management:
Wastes are not hazardous as defined by the Resource
Conservation and Recovery Act (RCRA) (40 CFR 261). Comply with state and local
regulations for disposal of fiber glass products. If you are
unsure of the regulations, contact vour local Public Health
Department, or the local office of the Environmental Protection Agency (EPA).
Use protective equipment as described in section 8 when handling loose
or unpackaged material.
Material should be kept dry, and protected from the
elements. Warehouse storage should be in accordance with package directions, if
any.
Summary:
Protective equipment should be provided as necessary to prevent irritation to the throat, eyes, and skin, and to keep exposures below the applicable exposure guidelines.
Goggles:
Safety glasses with sideshields are recommended to keep dust and fibers out of the eyes.
Gloves:
Leather or cotton gloves should be worn to prevent skin contact and irritation. Barriet creams may also be used to reduce skin contact and irritation.
Respirator:
Use a NIOSH approved dust/mist respirator to protect against nuisance dust and fibers. (Examples of NIOSH approved disposable dust/mist respirators for this type of exposure are the 3M 9900 and Moldex 2200 respirators.) Operations such as blowing, and spraying may generate airborne fiber concentrations requiring a higher level of respiratory protection. For exposures exceeding 10 fibers per cubic centimeter (f/cc), a NIOSH approved, reusable respirator with High Efficiency
Particulate Air (HEPA) filter cartridge should be used.
(Examples of NIOSH approved respirators of this type are the MSA Comfo 11 with
"H" cartridges, and the Survivair half-mask with #1090-00
cartridges.) Where formaldehyde exposure is suspected use a NIOSH approved
formaldehyde respirator with a dust/mist prefilter.
A respirator should be used if ventilation is unavailable,
or is inadequate for keeping dust and fiber levels below the applicable
exposure limits.
Ventilation:
Local exhaust ventilation should be provided at areas of cutting to remove airborne dust and fibers and to control the release of formaldehyde gas. General dilution ventilation should be provided as necessary to keep airborne dust, formaldehyde, and fibers below the applicable exposure limits and guidelines.
The need for ventilation systems should be evaluated by a
professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Other:
Loose fitting, long sleeved clothing should be worn to
protect skin from irritation. Exposed skin areas should be washed with soap and
warm water after handling or working with fiber glass. Clothing should be
washed separately from other clothes, and the washer should be rinsed
thoroughly (run empty for a complete wash cycle). This will reduce the chances
of fiber glass being transferred to other clothing.
Special
Considerations for repair/maintenance of contaminated equipment:
Use personal protective equipment as discussed above, vacuum equipment (where possible) before repair,'maintenance to remove excessive dust and loose fibers.
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Boiling
Pt. (°C/°F): |
Not determined |
Melting
Pt (°C/°F): |
>1600°F |
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Vapor
Pressure (mmHg): |
Not applicable |
Water Solubility (%): |
Nil |
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Specific
Gravity (water = 1): |
Variable |
Evaporation
rate (Butyl Acetate=1): |
Not applicable |
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Vapor
Density (Air=1): |
Not applicable |
%
Volatile by volume: |
0 |
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Total
VOC (g/liter): |
Not applicable |
pH: |
Not applicable |
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Solids
Content: |
Not applicable |
Saturation
in air (%): |
Not applicable |
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Viscosity: |
Not applicable |
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Appearance
and odor: White to yellow glass fiber mats in roll form with mild
formaldehyde odor. |
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Unusual Fire/Explosion
Hazards:
None.
Reactivity:
This product is not reactive.
Hazardous
Decomposition Products:
The decomposition products from this material are those that
would be expected from any organic (carbon containing) material, and are mainly
derived from pyrolysis, or burning, of the resin.
These decomposition products may include carbon dioxide,
carbon monoxide, carbon particles, formaldehyde, and traces of hydrogen
cyanide.
Toxicological and
Epidemiological Data
The hazards described in this document have been evaluated
based on a threshold of 1.0% of all hazardous ingredients.
Acute Effects:
The fibers from this product are mechanical irritants and
may cause transitory irritation to exposed areas such as eyes, skin, and upper
respiratory passages. The LD50 and LC50 (dose or
concentration lethal to 50% of a population of test animals) for this product
have not been determined.
Chronic Effects:
No chronic health effects are known to be associated with
exposure to continuous filament fiber glass. Results from epidemiologic studies
have not shown any increases in respiratory disease or cancer. The International
Agency for Reasearch on Cancer (IARC) has classified continuous filament fiber
glass as a group 3 carcinogen (not classifiable as to carcinogenicity). Because
of the large diameter of continuous filament fibers, these products are not
considered respirable. Formaldehyde gas has been related to the development of
nasal tumors in some experimental animal studies. OSHA considers formaldehyde
to have carcinogenic potential in humans. Exposure to formaldehyde can cause
skin or respiratory sensitization.
References:
A detailed listing of references on fiber glass health
effects can be found in Schullers
publication HSE-64C - "Health and Safety Aspects of
Fiber Glass" available free of charge from Schuller. Major references used
for the information contained in this MSDS are as follows:
"[ARC monographs on the evaluation of carcinogenic risks to humans:
Man-made mineral fibres and radon," Monograph No. 43, World Health
Organization, 1938.
Disposal Considerations
This product is not regulated as a hazardous waste
by the U.S. EPA under RCRA regulations. If you are unsure of the regulations,
contact your local Public Health Department, or the local office
of the Environmental Protection Agency (EPA).
Transport Information
Not classified a hazardous material by the U.S.
Department of Transportation
Regulatory Information
This product has not been classified a carcinogen by the
International Agency for Research on Cancer (IARC), the Occupational Safety and
Health Administration (OSHA), or the National Toxicology Program (NTP).
IARC, NTP and OSHA have classified formaldehyde gas as
having carcinogenic potential.
California Proposition 65 Listed Substances (Substance known
to the State of California to cause cancer): formaldehyde
This product is not subject to the reporting requirements of
section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 (SARA 111).
This product, and its components are listed on the following chemical
substance inventories: Toxic Substances Control Act Chemical Substance
Inventory (TSCA Inventory) Canadian Domestic Substance List (DSL)
The OSHA Permissible Exposure Limits (PELS) on this MSOS are based upon
the revised PELs of 1988. Currently, OSHA has been challenged by the courts to
provide more information about its update process. Until these issues are
resolved, Schuller will continue to list these PELS.
Miscellaneous
For additional information concerning this product, contact
the Schuller Product Information Center at: P.O. Box 5108, Denver, CO
80217-5108, or call toll-free (800)654-3103. (Outside the LJ.S. call collect:
(303)978-4900.)
MSDS Revision Summary
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Date |
MSDS No |
Reason |
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January 1, 1992 |
1014-01 |
Format revision |
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April 15, 1992 |
1014-02 |
Preparer/Manufacturer name change |
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August 31, 1992 |
1014-03 |
Sect. 2: New OSHA PEL for formaldehyde |
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December 15, 1992 |
1014-04 |
Sects. 3 & 11: Revision |
As of the date of preparation of this document, the foregoing
information is believed to be accurate and is provided in good faith to comply
with applicable federal and state law(s). However, no warranty or
representation with respect to such information is intended or given.